Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction
نویسندگان
چکیده
منابع مشابه
Non-rational covers of CP n ×CP m
The aim of this article is to provide further examples of higher dimensional varieties which are rationally connected, but not rational and not even ruled. The original methods of [Iskovskikh-Manin71; Clemens-Griffiths72] were further developed by many authors (for instance, [Beauville77; Iskovskikh80; Bardelli84]) and they give a quite complete picture in dimension three. [Corti96] is a recent...
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Interesting reactivity was observed in reactions of SO2 with [Zn(Cp*)2] and [(Cp*)ZnI-ZnI(Cp*)]. These reactions proceeded with insertion of SO2 into the Zn-C bonds. Spectacularly, the lability of the C-S bond in the O2SCp* ligands led to the thermal decomposition of [Zn(O2SCp*)2(tmeda)] to afford [Zn2(μ-SO3)(μ-S2O4)(tmeda)2].
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2012
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c2cc32690f